مقال
N-Ferrocenylmethyl-2-nitroaniline
Oumelkheir Rahim، Abdelhamid Khelef، Belgacem Terki، Mohammed Sadok Mahboub، Touhami Lanez
الملخّص
In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2)O(2))], the two cyclo-penta-dienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitro-benzenamine group, which is essentially perpendicular to the substituted cyclo-penta-dienyl ring, with an N-C(H(2))-C-C torsion angle of 89.8 (2)°. Intra-molecular N-H⋯O and N-H⋯N hydrogen bonds occur. In the crystal, weak C-H⋯O hydrogen bonds link adjacent mol-ecules.
التفاصيل
| اللغة الأصلية | English |
|---|---|
| المجلّة | Acta Crystallographica Section E Structure Reports Online |
| المجلّد | 68 |
| العدد | 10 |
| الصفحات | m1318 |
| الناشر | International Union of Crystallography |
| ISSN | 1600-5368 |
| DOI | 10.1107/s1600536812039177 |
| حالة النشر | منشور — 29 سبتمبر 2012 |
الكلمات المفتاحية
البصمة
- Crystal structures of chemical compounds
- Ferrocene Chemistry and Applications
- Crystallography and molecular interactions
- ferrocene complexes
- cyclopentadienyl ring
- dihedral angle
- intramolecular hydrogen bonding
- C-H⋯O hydrogen bonds
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Chemistry