Box–Behnken design with desirability function for methylene blue dye adsorption by microporous activated carbon from pomegranate peel using microwave assisted K 2 CO 3 activation
Abdallah Reghioua، Ali H. Jawad✉، Rangabhashiyam Selvasembian، Zeid A. ALOthman، Lee D. Wilson
الملخّص
This research aims to convert pomegranate peel (PP) into microporous activated carbon (PPAC) using a microwave assisted K2CO3 activation method. The optimum activation conditions were carried out with a 1:2 PP/K2CO3 impregnation ratio, radiation power 800 W, and 15 min irradiation time. The statistical Box–Behnken design (BBD) was employed as an effective tool for optimizing the factors that influence the adsorption performance and removal of methylene blue (MB) dye. The output data of BBD with a desirability function indicate a 94.8% removal of 100 mg/L MB at the following experimental conditions: PPAC dose of 0.08 g, solution pH of 7.45, process temperature of 32.1 °C, and a time of 30 min. The pseudo-second order (PSO) kinetic model accounted for the contact time for the adsorption of MB. At equilibrium conditions, the Freundlich adsorption isotherm describes the adsorption results, where the maximum adsorption capacity of PPAC for MB dye was 291.5 mg g−1. This study supports the utilization of biomass waste from pomegranate peels and conversion into renewable and sustainable adsorbent materials. As well, this work contributes to the management of waste biomass and water pollutant sequestration.
التفاصيل
| اللغة الأصلية | English |
|---|---|
| المجلّة | International Journal of Phytoremediation |
| المجلّد | 25 |
| العدد | 14 |
| الصفحات | 1988-2000 |
| الناشر | Taylor & Francis |
| ISSN | 1522-6514 · 1549-7879 |
| DOI | 10.1080/15226514.2023.2216304 |
| حالة النشر | منشور — 8 جوان 2023 |
الكلمات المفتاحية
أهداف التنمية المستدامة
- 12 — الاستهلاك والإنتاج المسؤولان
- 6 — المياه النظيفة والنظافة الصحية
البصمة
- Adsorption and biosorption for pollutant removal
- Coagulation and Flocculation Studies
- Environmental remediation with nanomaterials
- methylene blue adsorption
- pomegranate peel
- activated carbon
- microwave activation
- potassium carbonate activation
- biomass waste valorization
- dye removal
- adsorption kinetics
- Water Science and Technology
- Biomedical Engineering
- Environmental Science
- Engineering